2009年8月
Lactone Formation on Carbonaceous Materials during Electrochemical Oxidation
CHEMISTRY LETTERS
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- 巻
- 38
- 号
- 8
- 開始ページ
- 788
- 終了ページ
- 789
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.2009.788
- 出版者・発行元
- CHEMICAL SOC JAPAN
We focused on lactone formation during the electrochemical oxidation of highly oriented pyrolytic graphite (HOPG) as a model carbonaceous material for use in polymer electrolyte fuel cells in the potential range between 0.6 and 1.0 V against a normal hydrogen electrode. Lactone groups could be identified on the oxidized HOPG surface after holding at 1.0 V. Therefore, lactone groups are formed from the reaction between carbonyl groups and carboxylic groups as an intermediate in the electrochemical carbon oxidation reaction to CO2 evolution.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.2009.788
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000269899500015