2016年10月
Potential of Metal-Catalyzed C-C Single Bond Cleavage for Organic Synthesis
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- 巻
- 138
- 号
- 42
- 開始ページ
- 13759
- 終了ページ
- 13769
- 記述言語
- 英語
- 掲載種別
- 書評論文,書評,文献紹介等
- DOI
- 10.1021/jacs.6b01656
- 出版者・発行元
- AMER CHEMICAL SOC
Conventional organic synthesis has been mainly based upon the reactivities of pi-bonds and polar sigma-bonds. Carbon-carbon single bonds are nonpolar and generally far less reactive. Although they remain intact under most reaction conditions, it is possible to activate and cleave them if suitable organometallic compounds or metal catalysts are applied. Such C-C single bond cleavage reactions are attracting increasing attention in the context of synthetic chemistry because they provide a unique and more straightforward route from readily available substances to targets, while requiring significantly fewer steps. The present Perspective aims to exemplify the potential of metal-catalyzed C-C single bond cleavage for organic synthesis.
- リンク情報
- ID情報
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- DOI : 10.1021/jacs.6b01656
- ISSN : 0002-7863
- Web of Science ID : WOS:000386540500001