2016年4月
Markovnikov-Selective addition of fluorous solvents to unactivated olefins using a co catalyst
Chemical and Pharmaceutical Bulletin
- ,
- ,
- 巻
- 64
- 号
- 4
- 開始ページ
- 371
- 終了ページ
- 374
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1248/cpb.c15-01024
- 出版者・発行元
- PHARMACEUTICAL SOC JAPAN
© 2016 The Pharmaceutical Society of Japan. We developed an addition reaction of fluorous solvents to olefins using salen-cobalt (Co) complex, Nfluoro- 2,4,6- Trimethylpyridinium tetrafluoroborate, and 1,1,3,3- Tetramethyldisiloxane. This reaction condition was found to activate olefins, which enabled them to be attacked by 2,2,2- Trifluoroethanol (TFE) and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), both of which are electronically weak nucleophiles.
- リンク情報
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- DOI
- https://doi.org/10.1248/cpb.c15-01024
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/27039835
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000373246300012&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84964788399&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84964788399&origin=inward
- ID情報
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- DOI : 10.1248/cpb.c15-01024
- ISSN : 0009-2363
- eISSN : 1347-5223
- PubMed ID : 27039835
- SCOPUS ID : 84964788399
- Web of Science ID : WOS:000373246300012