論文

査読有り
2019年6月

Force-driven reversible liquid-gas phase transition mediated by elastic nanosponges

NATURE COMMUNICATIONS
  • Nomura, Keita
  • ,
  • Nishihara, Hirotomo
  • ,
  • Yamamoto, Masanori
  • ,
  • Gabe, Atsushi
  • ,
  • Ito, Masashi
  • ,
  • Uchimura, Masanobu
  • ,
  • Nishina, Yuta
  • ,
  • Tanaka, Hideki
  • ,
  • Miyahara, Minoru T.
  • ,
  • Kyotani, Takashi

10
1
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1038/s41467-019-10511-7
出版者・発行元
NATURE PUBLISHING GROUP

Nano-confined spaces in nanoporous materials enable anomalous physicochemical phenomena. While most nanoporous materials including metal-organic frameworks are mechanically hard, graphene-based nanoporous materials possess significant elasticity and behave as nanosponges that enable the force-driven liquid-gas phase transition of guest molecules. In this work, we demonstrate force-driven liquid-gas phase transition mediated by nanosponges, which may be suitable in high-efficiency heat management. Compression and free-expansion of the nanosponge afford cooling upon evaporation and heating upon condensation, respectively, which are opposite to the force-driven solid-solid phase transition in shape-memory metals. The present mechanism can be applied to green refrigerants such as H2O and alcohols, and the available latent heat is at least as high as 192 kJ kg(-1). Cooling systems using such nanosponges can potentially achieve high coefficients of performance by decreasing the Young's modulus of the nanosponge.

リンク情報
DOI
https://doi.org/10.1038/s41467-019-10511-7
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000471757900001&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-85067447256&partnerID=MN8TOARS
ID情報
  • DOI : 10.1038/s41467-019-10511-7
  • ISSN : 2041-1723
  • ORCIDのPut Code : 86494072
  • SCOPUS ID : 85067447256
  • Web of Science ID : WOS:000471757900001

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