Papers

Peer-reviewed
Dec, 2017

Infrared spectroscopic study of OH defects in monazite

European Journal of Mineralogy
  • Abe Takeyasu
  • ,
  • Kuribayashi Takahiro*
  • ,
  • Nakamura Michihiko*

Volume
29
Number
6
First page
949
Last page
957
Language
English
Publishing type
DOI
10.1127/ejm/2017/0029-2663

Polarised infrared spectra of synthetic single crystals and radiation-damaged natural samples were collected to examine hydroxyl incorporation in monazite. The IR spectra of pure synthetic monazite contain two OH stretching bands at 3163 and 3335 cm$^{-1}$ with contrasting bandwidths of 40 and 90 cm$^{-1}$, respectively. The two OH bands show strong pleochroism and dominant infrared absorption in the Y direction. The IR spectra of natural monazite contains a weak pleochroic OH band centered around 3400 cm$^{-1}$ with a bandwidth of more than 200 cm$^{-1}$. During step-heating experiments, this broad OH band split into several bands, and these bands differ from those observed in the spectra of synthetic samples. The OH stretching signals in the spectra of both natural and synthetic samples disappeared after heating at 1000$^{\circ}$C. Based on these results, OH defects in natural monazite arise because of secondary hydration facilitated by radiation damage, as in the case of natural zircon and xenotime.

Link information
DOI
https://doi.org/10.1127/ejm/2017/0029-2663
URL
https://jopss.jaea.go.jp/search/servlet/search?5059455
ID information
  • DOI : 10.1127/ejm/2017/0029-2663
  • ISSN : 0935-1221

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