MISC

2001年7月

Effects of intergranular phase chemistry on the microstructure and mechanical properties of silicon carbide ceramics densified with rare-earth oxide and alumina additions

JOURNAL OF THE AMERICAN CERAMIC SOCIETY
  • Y Zhou
  • ,
  • K Hirao
  • ,
  • M Toriyama
  • ,
  • Y Yamauchi
  • ,
  • S Kanzaki

84
7
開始ページ
1642
終了ページ
1644
記述言語
英語
掲載種別
DOI
10.1111/j.1151-2916.2001.tb00891.x
出版者・発行元
AMER CERAMIC SOC

Based on the processing strategy of improving the mechanical properties of liquid-phase-sintered materials by modifying the secondary phase chemistry, four rare-earth oxides (RE2O3, RE = La, Nd, Y, and Yb), in combination with alumina, were used as sintering aids for a submicrometer-size beta -SIC powder. Doped with 5 vol% RE2O3 + Al2O3 additives, all specimens were hot-pressed-to near full-densities at 1800 degreesC, and they exhibited similar microstructures and grain Size distributions. The SiC grains in all specimens revealed a core-rim structure after being plasma-etched, indicating that they were densified via the same solution-reprecipitation mechanism. It was found that a decrease in the cationic radius of the rare-earth oxides was accompanied by an increase in Young's modulus, hardness, and flexural strength of the SiC ceramics, whereas the fracture toughness was improved by incorporating rare-earth oxides of larger cationic radius. The changes in the mechanical properties were attributed to the difference in the chemistry of the intergranular phases in the four ceramics.

リンク情報
DOI
https://doi.org/10.1111/j.1151-2916.2001.tb00891.x
CiNii Articles
http://ci.nii.ac.jp/naid/80012491117
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000169848300041&DestApp=WOS_CPL
ID情報
  • DOI : 10.1111/j.1151-2916.2001.tb00891.x
  • ISSN : 0002-7820
  • CiNii Articles ID : 80012491117
  • identifiers.cinii_nr_id : 9000239248799
  • Web of Science ID : WOS:000169848300041

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