Apr, 2002
Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homocoupling of aryl halides
SYNLETT
- ,
- ,
- Volume
- Number
- 4
- First page
- 637
- Last page
- 639
- Language
- English
- Publishing type
- Publisher
- GEORG THIEME VERLAG KG
A combination of tetrakis(dimethylamino)ethylene (TDAE) and palladium catalysts promoted reductive homo-coupling of aryl halides efficiently to afford the corresponding biaryls in good to quantitative yields. TDAE acted as a very mild reductant, and easily reducible functional groups, such as a nitro, formyl, ester, or nitrite group, remained unchanged.
- Link information
- ID information
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- ISSN : 0936-5214
- Web of Science ID : WOS:000174934200028