論文

査読有り
2009年2月

Quasielastic neutron scattering investigation of motion of water molecules in n-propyl alcohol-water mixture

JOURNAL OF CHEMICAL PHYSICS
  • Masaru Nakada
  • ,
  • Kenji Maruyama
  • ,
  • Osamu Yamamuro
  • ,
  • Masakatsu Misawa

130
7
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1063/1.3073881
出版者・発行元
AMER INST PHYSICS

The dynamics of water molecules in the n-propyl alcohol-water mixtures is investigated by using quasielastic neutron scattering measurements. The dynamic structure factor S(Q,E) obtained from incoherent scattering of hydrogen atoms of water is fitted with jump diffusion and relaxing cage models. The diffusion constant obtained from the relaxing cage model, which gives better fitting with S(Q,E), shows better agreement to the experimental value than that of jump diffusion model. The dependence of translational relaxation time tau(T)(Q) and stretched exponent beta(T)(Q) on the fraction of hydrophobic hydrating water molecules in the solution is discussed.

リンク情報
DOI
https://doi.org/10.1063/1.3073881
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000263599300022&DestApp=WOS_CPL
ID情報
  • DOI : 10.1063/1.3073881
  • ISSN : 0021-9606
  • Web of Science ID : WOS:000263599300022

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