2001年2月
Incompatibility of polyelectrolyte solutions - mixed solutions of PSSNa and PVSNa
POLYMER
- ,
- ,
- ,
- 巻
- 42
- 号
- 4
- 開始ページ
- 1501
- 終了ページ
- 1505
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/S0032-3861(00)00509-7
- 出版者・発行元
- ELSEVIER SCI LTD
The compatibility of PSSNa and PVSNa in aqueous solution has been studied. PSSNa and PVSNa are compatible when the total concentration is less than 1.0 mol/l, but phase separation occurs when the total concentration exceeds 1.0 mol/l. The cloud point curve is of a typical UCST type. Addition of salt causes a shift of the boundary toward a lower concentration. It may be considered that these new critical phenomena are a reflection of the balance between electrostatic and non-electrostatic interactions. The time evolving processes of the phase separation has also been investigated. The characteristic behavior of spinodal decomposition is observed when the temperature of a mixed solution is jumped down passing through the critical point. (C) 2000 Elsevier Science Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S0032-3861(00)00509-7
- ISSN : 0032-3861
- J-Global ID : 200902179713720641
- Web of Science ID : WOS:000165303300022