2002年
Hydration enthalpy of hydrotalcite low-temperature metaphases
Journal of Mineralogical and Petrological Sciences
- ,
- ,
- ,
- 巻
- 97
- 号
- 1
- 開始ページ
- 1
- 終了ページ
- 6
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.2465/jmps.97.1
- 出版者・発行元
- Tohoku University
Enthalpies of hydration of low-temperature hydrotalcite(HT) metaphases have been measured by means of the adiabatic water-vapor absorption calorimeter. The metaphases were characterized by the Mg/Al ratio of 3:1 and CO3 2- interlayer group. The hydration heat for HT-B (partially dehydroxylated HT with bidentate bonded CO3 2-) is 2-3 times larger than that of HT-D (dehydrated HT), if they are treated at the same dehydration temperature. Large absolute values of hydration heat, namely 398±4 and 508±10Jg-1, were obtained for the HT-B at respective low dehydration temperatures, 70 and 110°C. This may promise the HT-B to be a new prospective heat exchanger usable at relatively low temperatures.
- リンク情報
- ID情報
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- DOI : 10.2465/jmps.97.1
- ISSN : 1349-3825
- ISSN : 1345-6296
- SCOPUS ID : 0141694441