2004年12月
Tetrabutylammonium phosphomolybdate on fluorapatite: an efficient solid catalyst for solvent-free selective oxidation of sulfides
TETRAHEDRON LETTERS
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- 巻
- 45
- 号
- 52
- 開始ページ
- 9513
- 終了ページ
- 9515
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.tetlet.2004.11.002
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
A new synthetic method of sulfoxides and sulfones using solvent-free oxidations of sulfides with urea-hydrogen peroxide complex (urea-H2O2) and tetrabutylammonium phosphomolybdate catalyst on fluorapatite ((Bu4N)(3)[PMo12O40]/FAp). In the solid-phase system the oxidations of aromatic and alkyl sulfides proceeded at 4-25degreesC and the corresponding sulfoxides or sulfones were selectively obtained in good yields by controlling the amount of urea-H2O2. (C) 2004 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2004.11.002
- ISSN : 0040-4039
- CiNii Articles ID : 80017028901
- Web of Science ID : WOS:000225623200004