1990年
Multiplet structure in core-level XPS OF HIGH-Tc material La2CuO4 and related Cu-compounds
Journal of Electron Spectroscopy and Related Phenomena
- ,
- 巻
- 52
- 号
- C
- 開始ページ
- 313
- 終了ページ
- 322
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/0368-2048(90)85028-8
In this study, we discuss the multiplet structure observed in the Cu 2p- and 3p-XPS in La2CuO4, CuO and Cu dihalides using the single-site Anderson model. We take into account the multiplet coupling between a Cu 3d hole and a core hole, and the anisotropic hybridization between the 3d hole and O 2p valence band holes. As a result, we show that the multiplet structure is strongly affected by the anisotropic hybridization. We discuss the local electronic structures around the Cu atom by analyzing the deviation of the core-level XPS in these materials from the XPS in free Cu2+ ion. © 1990.
- ID情報
-
- DOI : 10.1016/0368-2048(90)85028-8
- ISSN : 0368-2048
- SCOPUS ID : 0001747890