2014年1月12日
Dual gold catalysis: Synthesis of polycyclic compounds via C-H insertion of gold vinylidenes
Chemistry - A European Journal
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- 巻
- 20
- 号
- 49
- 開始ページ
- 16331
- 終了ページ
- 16336
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/chem.201404987
- 出版者・発行元
- Wiley-VCH Verlag
New and interesting polycyclic compounds have been synthesized from non-conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the backbone and the accompanying Thorpe-Ingold effect enabled the unprecedented insertion of sp3 and sp2 C-H bonds that for the first time were incorporated within the backbone of the diyne system and allowed the construction of complex polycyclic carbon scaffolds inaccessible by previous approaches in which the C-H bonds for the insertion were situated at the other end of the alkyne.
- ID情報
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- DOI : 10.1002/chem.201404987
- ISSN : 1521-3765
- ISSN : 0947-6539
- PubMed ID : 25352494
- SCOPUS ID : 84915747399