論文

査読有り
2005年12月

Development of useful reactions based on the novel reactivities of allenic compounds and their application to tandem cyclizations

YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN
  • H Ohno

125
12
開始ページ
899
終了ページ
925
記述言語
日本語
掲載種別
DOI
10.1248/yakushi.125.899
出版者・発行元
PHARMACEUTICAL SOC JAPAN

This review highlights a recent study on allenic compounds by the author's group. In the first section, the organocopper-mediated ring-opening reaction of ethynylaziridines and palladium-catalyzed reductive synthesis of allenes are described. In the second section, palladium-catalyzed stereoselective cyclization of allenes, including the tandem reaction, leading to aziridines, pyrrolidines, benzoisoindoles, and cyclopropanes is presented. The final section reviews aziridination and medium-ring formation due to the intramolecular reaction of bromoallenes. The latter reaction is based on the author's recent discovery that bromoallenes can act as allylic dication equivalents in the presence of a palladium catalyst and alcohol.

リンク情報
DOI
https://doi.org/10.1248/yakushi.125.899
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/16327237
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000234103600001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1248/yakushi.125.899
  • ISSN : 0031-6903
  • PubMed ID : 16327237
  • Web of Science ID : WOS:000234103600001

エクスポート
BibTeX RIS