Papers

Peer-reviewed
May, 2009

Effect of iron content on electrical conductivity of ringwoodite, with implications for electrical structure in the transition zone

PHYSICS OF THE EARTH AND PLANETARY INTERIORS
  • Takashi Yoshino
  • ,
  • Tomoo Katsura

Volume
174
Number
1-4
First page
3
Last page
9
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.pepi.2008.09.015
Publisher
ELSEVIER SCIENCE BV

Electrical conductivity of ringwoodite with various iron contents [Fe/Fe + Mg) = 0.09, 0.2 and 0.3] was measured at pressure (20 GPa) and temperature (up to 1900 K) conditions of the lower part of the mantle transition zone in a Kawai-type multi-anvil apparatus. The conductivity increased with increasing total iron content. All electrical conductivity data were fitted to the formula of electrical conductivity sigma = sigma(0) X-Fe exp(-H/kT), where sigma(0) is the pre-exponential term, X-Fe is the mole fraction of iron content in the Mg site, H is the activation enthalpy, k is the Boltzmann constant and T is absolute temperature. The activation enthalpy becomes higher at a certain temperature. At high temperatures, the activation enthalpy decreased from 1.44 to 0.92 eV with increasing total Fe content. At low temperatures less than 1000 K, the activation enthalpy also decreases from 1.15 to 0.74 eV with total Fe content. Dependence of the activation enthalpy on Fe content suggests that the dominant mechanism of charge transport is Fe2+-Fe3+ hopping (small polaron). Recent electrical conductivity-depth profiles of the transition zone beneath the Pacific Ocean obtained from the electromagnetic induction Study shows that the conductivity values between 520 and 660 km depths may be explained by ringwoodite with Fe/Fe + Mg) = 0.10. On the other hand, assuming a normal geotherm, conductivity values beneath the continent or stable craton are considerably lower than those of ringwoodite with Fe/(Fe + Mg) = 0.10. Taking into consideration results from the global seismic tomographic studies, relatively low conductivity in these regions can be explained by the existence of a cooler region compared with the surrounding mantle, rather than the presence of iron-poor ringwoodite, or a combination of both. (C) 2008 Elsevier B.V. All rights reserved.

Link information
DOI
https://doi.org/10.1016/j.pepi.2008.09.015
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000266836700002&DestApp=WOS_CPL
URL
http://www.scopus.com/inward/record.url?eid=2-s2.0-67349219405&partnerID=MN8TOARS
URL
http://orcid.org/0000-0002-5422-7396
ID information
  • DOI : 10.1016/j.pepi.2008.09.015
  • ISSN : 0031-9201
  • eISSN : 1872-7395
  • ORCID - Put Code : 58517935
  • SCOPUS ID : 67349219405
  • Web of Science ID : WOS:000266836700002

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