2006年
Redox behavior and catalytic oxidation reactions of alcohols by a new ruthenium(III)-dioxolene-amine complex of bis(2-pyridylmethyl)-2-aminoethylamine
Bulletin of the Chemical Society of Japan
- ,
- ,
- 巻
- 79
- 号
- 5
- 開始ページ
- 745
- 終了ページ
- 747
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/bcsj.79.745
A ruthenium-dioxolene-amine complex, [RuIII(NH 2-L)(Bu2sq)](PF6)2·0.5H 2O (NH2-L = bis(2-pyridylmethyl)-2-aminoethylamine, Bu2sq- = 3,5-di-tert-butylsemiquinonate), was newly prepared. The complex undergoes spontaneous one-electron reduction under basic conditions in MeOH and works as an electrocatalyst in the oxidation of benzyl alcohol to benzaldehyde under electrolysis at +0.4 V (vs SCE). © 2006 The Chemical Society of Japan.
- リンク情報
- ID情報
-
- DOI : 10.1246/bcsj.79.745
- ISSN : 0009-2673
- ISSN : 1348-0634
- SCOPUS ID : 33750611150