論文

査読有り
2008年10月

Tear Velocity Dependence of High-Strength Double Network Gels in Comparison with Fast and Slow Relaxation Modes Observed by Scanning Microscopic Light Scattering

MACROMOLECULES
  • Hidemitsu Furukawa
  • ,
  • Rikimaru Kuwabara
  • ,
  • Yoshimi Tanaka
  • ,
  • Takayuki Kurokawa
  • ,
  • Yang-Ho Na
  • ,
  • Yoshihito Osada
  • ,
  • Jian Ping Gong

41
19
開始ページ
7173
終了ページ
7178
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/ma800821j
出版者・発行元
AMER CHEMICAL SOC

To investigate the mechanical strength of double network (DN) gels in a wide dynamical range, the gel solvent was replaced with viscous solvents-ethylene glycol and glycerol-and with their mixtures with water. The viscosity dependence of fracture energy in a tearing test was weak but demonstrated the existence of characteristic tear velocity for maximum fracture energy as a function of solvent viscosity. Fast and slow relaxation modes in the gels' dynamics were simultaneously observed by scanning microscopic light scattering, which reveals that the DN-gel structure stays unperturbed by the solvent change. These results implied that the solvent viscosity weakly affect the toughness and structure of the DN gels. Further, we demonstrated that the effect of solvent viscosity on the fracture energy can be incorporated into a scaled tear velocity that distributes over 6 orders of magnitude. We concluded that the viscous friction between polymer and solvent is not particularly significant for the energy dissipation of DN-gel fracture.

リンク情報
DOI
https://doi.org/10.1021/ma800821j
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000259859800045&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/ma800821j
  • ISSN : 0024-9297
  • Web of Science ID : WOS:000259859800045

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