Dec, 1992
STRUCTURAL AND SUPERCONDUCTING PROPERTIES OF IODINE-INTERCALATED BI2SR2CA1-XYXCU2OZ
PHYSICA C
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- Volume
- 204
- Number
- 1-2
- First page
- 65
- Last page
- 70
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1016/0921-4534(92)90573-U
- Publisher
- ELSEVIER SCIENCE BV
The structual and superconducting properties of Bi2Sr2Ca1-xYxCu2Oz intercalated with iodine between the Bi-O bilayers were studied. Formation of the stage-1 compound was verified by X-ray analysis, TG analysis and TEM observation. Expansion of the c-axis, which is caused by increase in the distance of the BiO-BiO layers, decreases with decreasing intercalated iodine concentration down to 60%. The expansion of the c-axis of fully intercalated compounds increases with increasing Y content from 7.2 angstrom for x = 0 to 7.5 angstrom for x = 1.O. The temperature dependence of resistivity showed that iodine-doped samples (x = 0 and 0.4) were more semiconductive than non-doped samples. The T(c) of the IBi2Sr2Ca1-xYxCu2Oz series in the over-doped region was reduced by 2-10 K compared with non-intercalated samples.
- Link information
- ID information
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- DOI : 10.1016/0921-4534(92)90573-U
- ISSN : 0921-4534
- Web of Science ID : WOS:A1992KF57200009