MISC

2007年

Fluctuation effects on viscoelastic properties of diblock copolymer solutions in disordered state

POLYMER JOURNAL
  • Yoshiaki Takahashi
  • ,
  • Yuki Ojika
  • ,
  • Yoshihiko Akazawa
  • ,
  • Atsushi Takano
  • ,
  • Yushu Matsushita

39
6
開始ページ
509
終了ページ
513
記述言語
英語
掲載種別
DOI
10.1295/polymj.PJ2006157
出版者・発行元
SOC POLYMER SCIENCE JAPAN

Viscoelastic properties of three poly(styrene-d(8)-block-isoprene)s in dioctyl phthalate are measured under oscillatory and steady shear flows in the disordered state, to examine the fluctuation effects on zero shear viscosity) eta(0) and steady state compliance J(e) based on the effective interaction parameter (chi N)(eff). Flow-induced microphase separation is not observed when (chi N)(eff) is lower than 9.9. Enhancement of eta(0) and J(e) due to the fluctuation effects, which is more obvious for J(e), are observed in oscillatory flow, while suppression of the fluctuation effects are observed in steady shear flow, which is confirmed by small angle neutron scattering measurements. Comparing these results with those for poly(styrene-block-2-vinylpyridine)s (SP), it is concluded that the viscosity enhancement due to the fluctuation effects slightly depend on component viscosities. When viscosity ratio of components is close to 1 (i.e., SP), the viscosity enhancement is negligible. On the other hand, enhancement of reduced steady state compliance J(eR) seems to be insensitive to the viscosity ratio of components.

リンク情報
DOI
https://doi.org/10.1295/polymj.PJ2006157
CiNii Articles
http://ci.nii.ac.jp/naid/40015410929
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000248369100005&DestApp=WOS_CPL
ID情報
  • DOI : 10.1295/polymj.PJ2006157
  • ISSN : 0032-3896
  • CiNii Articles ID : 40015410929
  • Web of Science ID : WOS:000248369100005

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