2020年11月
Sequential Chiral Induction and Regulator-Assisted Chiral Memory of Pillar[5]arenes
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
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- 巻
- 59
- 号
- 46
- 開始ページ
- 20353
- 終了ページ
- 20356
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.202010050
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Chirality transfer is widely observed in life processes, and many artificial chiral transfer systems have been developed. In these systems, chiral information is transferred from chiral inducers to chiral acceptors by a direct chiral induction process and a direct chiral memorization process. We have developed ternary nondirect chiral transfer systems based on pillar[5]arenes, in which a third factor was introduced as a regulator. The planar chirality of an acceptor was induced and memorized by a chiral inducer with precise control by a regulator. In the chiral induction period, the feed sequence of the chiral inducer and regulator affected the chiral induction behavior of the chiral acceptor. The chiral memory ability of the acceptor was substantially improved by the combined action of the chiral inducer and regulator.
- リンク情報
- ID情報
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- DOI : 10.1002/anie.202010050
- ISSN : 1433-7851
- eISSN : 1521-3773
- Web of Science ID : WOS:000575555300001