論文

2020年11月

Sequential Chiral Induction and Regulator-Assisted Chiral Memory of Pillar[5]arenes

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  • Shixin Fa
  • ,
  • Kouichi Egami
  • ,
  • Keisuke Adachi
  • ,
  • Kenichi Kato
  • ,
  • Tomoki Ogoshi

59
46
開始ページ
20353
終了ページ
20356
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/anie.202010050
出版者・発行元
WILEY-V C H VERLAG GMBH

Chirality transfer is widely observed in life processes, and many artificial chiral transfer systems have been developed. In these systems, chiral information is transferred from chiral inducers to chiral acceptors by a direct chiral induction process and a direct chiral memorization process. We have developed ternary nondirect chiral transfer systems based on pillar[5]arenes, in which a third factor was introduced as a regulator. The planar chirality of an acceptor was induced and memorized by a chiral inducer with precise control by a regulator. In the chiral induction period, the feed sequence of the chiral inducer and regulator affected the chiral induction behavior of the chiral acceptor. The chiral memory ability of the acceptor was substantially improved by the combined action of the chiral inducer and regulator.

リンク情報
DOI
https://doi.org/10.1002/anie.202010050
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000575555300001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/anie.202010050
  • ISSN : 1433-7851
  • eISSN : 1521-3773
  • Web of Science ID : WOS:000575555300001

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