2008年10月
Intramolecular arylcyanation of alkenes catalyzed by nickel/AlMe2CI
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- ,
- ,
- ,
- 巻
- 130
- 号
- 39
- 開始ページ
- 12874
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ja805088r
- 出版者・発行元
- AMER CHEMICAL SOC
A catalyst system derived from nickel and cocatalytic AlMe2Cl effects the intramolecular arylcyanation of alkenes. The reaction takes place in an exclusive exo-dig manner to give a wide range of nitrites having a benzylic quaternary carbon in good yields. Detailed investigations are described on the scope and mechanism as well as preliminary results on the asymmetric version of the reaction to provide novel access to chiral quaternary stereocenters.
- リンク情報
- ID情報
-
- DOI : 10.1021/ja805088r
- ISSN : 0002-7863
- Web of Science ID : WOS:000259553700019