2018年7月26日
Rational Synthesis of Antiaromatic 5,15-Dioxaporphyrin and Oxidation into β,β-Linked Dimers
Angewandte Chemie - International Edition
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- 巻
- 57
- 号
- 31
- 開始ページ
- 9728
- 終了ページ
- 9733
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201804648
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 5,15-Dioxaporphyrin was synthesized for the first time by a nucleophilic aromatic substitution reaction of a nickel bis(α,α′-dibromodipyrrin) complex with benzaldoxime, followed by an intramolecular annulation of the α-hydroxy-substituted intermediate. This unprecedented molecule is a 20π-electron antiaromatic system, in terms of Hückel's rule of aromaticity, because lone pair electrons of oxygen atoms are incorporated into the 18π-electron conjugated system of the porphyrin. A theoretical analysis based on the gauge-including magnetically induced current method confirmed its antiaromaticity and a dominant inner ring pathway for the ring current. The unique reactivity of 5,15-dioxaporphyrin forming a β,β-linked dimer upon oxidation was also revealed.
- リンク情報
- ID情報
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- DOI : 10.1002/anie.201804648
- ISSN : 1433-7851
- eISSN : 1521-3773
- PubMed ID : 29901249
- SCOPUS ID : 85050488217