2011年5月
Synthesis Of pi-Expanded O-Chelated Boron–Dipyrromethene As An NIR Dye
ElsevierTetrahedron
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- 巻
- 67
- 号
- 18
- 開始ページ
- 3187
- 終了ページ
- 3193
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.tet.2011.03.016
A π-expanded BODIPY dye with an intramolecular boronate skeleton was synthesized by retro Diels-Alder reaction of the bicyclo[2.2.2]octadiene (BCOD)-fused BODIPY and the subsequent O-chelation. The photophysical and electrochemical properties were examined by UV-vis, fluorescence, CV measurements, and DFT calculation. This BODIPY exhibited the absorption and emission over a visible-NIR region at 600-850 nm. O-chelated BODIPY showed a bathocromic shift compared to F-BODIPYs. This dye showed a bright fluorescence emission at 733 nm with the high Φ value of 0.58. © 2011 Elsevier Ltd. All rights reserved.
- リンク情報
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- DOI
- https://doi.org/10.1016/j.tet.2011.03.016
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000290075200005&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&scp=79954420632&origin=inward
- ID情報
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- DOI : 10.1016/j.tet.2011.03.016
- ISSN : 0040-4020
- SCOPUS ID : 79954420632
- Web of Science ID : WOS:000290075200005