2010年2月
Fully pi-Conjugated Helices from Oxidative Cleavage of meso-Aryl-Substituted Expanded Porphyrins
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- ,
- ,
- 巻
- 132
- 号
- 7
- 開始ページ
- 2128
- 終了ページ
- +
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1021/ja909929s
- 出版者・発行元
- AMER CHEMICAL SOC
Fully pi-conjugated oligopyrromethene helices coiling two Cu(II) ions were obtained from oxidative cleavage of expanded porphyrins. The Smoothly conjugated backbone structures, distinct near-IR absorption bands, and extended spin-density distributions demonstrated the effective pi-electron delocalization over the whole helices. Magnetic susceptibility and electron spin resonance measurements revealed the antiferromagnetic interaction between the internal Cu(II) ions.
- リンク情報
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- DOI
- https://doi.org/10.1021/ja909929s
- CiNii Articles
- http://ci.nii.ac.jp/naid/80020919903
- PubMed
- https://www.ncbi.nlm.nih.gov/pubmed/20108909
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000275085100014&DestApp=WOS_CPL
- ID情報
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- DOI : 10.1021/ja909929s
- ISSN : 0002-7863
- CiNii Articles ID : 80020919903
- PubMed ID : 20108909
- Web of Science ID : WOS:000275085100014