Tamio Hayashi

Profile Information

Affiliation: Professor,Professor, Graduate School of Science, Division of Chemistry, Graduate School of Science Department of Chemistry, Kyoto University

Degree: Doctor of Engineering(Kyoto University)
Doctor of Engineering

J-GLOBAL ID: 200901034883975286
researchmap Member ID: 1000001042

External link: http://kuchem.kyoto-u.ac.jp/orgchem/index-j.html

Research Interests

Research Areas

Research History

1989 - 1993

Hokkaido University
1989 - 1993

Hokkaido University, Professor
1975 - 1988

京都大学助手
1975 - 1988

Kyoto University, Research Assistant

Education

- 1975

Kyoto University
- 1975

Graduate School, Division of Engineering, Kyoto University
- 1970

Faculty of Engineering, Kyoto University
- 1970

Faculty of Engineering, Kyoto University

Awards

2008

Arthur C. Cope Scholar Award
2008

Arthur C. Cope Scholar Award
2007

有機合成化学協会高砂香料国際賞「野依賞」
2007

Ryoji Noyori Prize
2005

Molecular Chirality Award
2005

Molecular Chirality Award
2004

Thomson Scientific Research Front Award
2004

Thomson Scientific Research Front Award
2003

日本化学会賞
2003

The Chemical Society of Japan Award
1991

日本IBM科学賞
1991

the IBM (Japan) Prize
1983

有機合成化学奨励賞
1983

Award for Young Chemists of the Society of Synthetic Organic Chemistry, Japan

Misc.

202

Palladium-catalyzed Decarboxylative [4+1] Cyclization of gamma-Methylidene-delta-valerolactones with Isocyanides

Soyoung Park, Ryo Shintani, Tamio Hayashi

CHEMISTRY LETTERS, 38(3) 204-205, Mar, 2009
Tuning the Chiral Environment of C-2-Symmetric Diene Ligands: Development of 3,7-Disubstituted Bicyclo[3.3.1]nona-2,6-dienes

Ryo Shintani, Yoshitaka Ichikawa, Keishi Takatsu, Fu-Xue Chen, Tamio Hayashi

JOURNAL OF ORGANIC CHEMISTRY, 74(2) 869-873, Jan, 2009
Stereoselective Synthesis of Nipecotic Acid Derivatives via Palladium-Catalyzed Decarboxylative Cyclization of gamma-Methylidene-delta-valerolactones with Imines

Ryo Shintani, Masataka Murakami, Tamio Hayashi

ORGANIC LETTERS, 11(2) 457-459, Jan, 2009
Simple chiral diene ligands provide high enantioselectivities in transition-metal-catalyzed conjugate addition reactions

Kazuhiro Okamoto, Tamio Hayashi, Viresh H. Rawal

ORGANIC LETTERS, 10(19) 4387-4389, Oct, 2008
Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes

Takahiro Nishimura, Eiji Tsurumaki, Takahiro Kawamoto, Xun-Xiang Guo, Tamio Hayashi

ORGANIC LETTERS, 10(18) 4057-4060, Sep, 2008
C(2)-Symmetric tetrafluorobenzobarrelenes as highly efficient ligands for the iridium-catalyzed asymmetric annulation of 1,3-dienes with 2-formylphenylboron reagents

Takahiro Nishimura, Yuichi Yasuhara, Makoto Nagaosa, Tamio Hayashi

TETRAHEDRON-ASYMMETRY, 19(15) 1778-1783, Aug, 2008
Chiral tetrafluorobenzobarrelenes as highly efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids

Takahiro Nishimura, Makoto Nagaosa, Tamio Hayashi

CHEMISTRY LETTERS, 37(8) 860-861, Aug, 2008
Ruthenium-catalyzed 1,4-addition of organoboronic acids to alpha,beta-unsaturated ketones

Ryo Shintani, Tamio Hayashi

CHEMISTRY LETTERS, 37(7) 724-725, Jul, 2008
Cobalt-catalyzed coupling of alkenyl triflates with aryl and alkenyl Grignard reagents

Eiji Shirakawa, Yusuke Imazaki, Tamio Hayashi

CHEMISTRY LETTERS, 37(6) 654-655, Jun, 2008
Fe-Cu cooperative catalysis in the isomerization of alkyl Grignard reagents

Eiji Shirakawa, Daiji Ikeda, Shigeru Yamaguchi, Tarnio Hayashi

CHEMICAL COMMUNICATIONS, (10) 1214-1216, Mar, 2008
Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage

Ryo Shintani, Keishi Takatsu, Tamio Hayashi

ORGANIC LETTERS, 10(6) 1191-1193, Mar, 2008
Steric tuning of silylacetylenes and chiral phosphine ligands for rhodium-catalyzed asymmetric conjugate alkynylation of enones

Takahiro Nishimura, Xun-Xiang Guo, Nanase Uchiyama, Taisuke Katoh, Tamio Hayashi

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130(5) 1576-+, Feb, 2008
Rhodium/chiral diene-catalyzed asymmetric 1,4-addition of arylboronic acids to arylmethylene cyanoacetates

Sebastian Soergel, Norihito Tokunaga, Keigo Sasaki, Kazuhiro Okamoto, Tamio Hayashi

ORGANIC LETTERS, 10(4) 589-592, Feb, 2008
Rhodium-catalyzed rearrangement of aryl bis(alkynyl) carbinols to 3-alkynyl-1-indanones

Ryo Shintani, Keishi Takatsu, Taisuke Katoh, Takahiro Nishimura, Tamio Hayashi

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47(8) 1447-1449, 2008
Platinum-catalyzed generation of silylenes from hydrodisilanes and their addition to alpha,beta-unsaturated ketones

Kazuhiro Okamoto, Tamio Hayashi

CHEMISTRY LETTERS, 37(1) 108-109, Jan, 2008
Rhodium-Catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines

Yoshiaki Nakao, Masahide Takeda, Jinshui Chen, Tamejiro Hiyama, Yoshitaka Ichikawa, Ryo Shintani, Tamio Hayashi

Chem. Lett., 37(3) 290-291, 2008
Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes

Takahiro Nishimura, Xun-Xiang Guo, Tamio Hayashi

CHEMISTRY-AN ASIAN JOURNAL, 3(8-9) 1505-1510, 2008
Platinum-catalyzed 1,4-Addition of Arylboronic Acids to b-Substituted a,b-Unsaturated Ketones

Tamio Hayashi, Keigo Sasaki

Chem. Lett., 37(8) 842-843, 2008
Palladium-Catalyzed Asymmetric [4 + 2] Cycloaddition of g-Methylidene-d-valerolactones with Isocyanates: Conversion of Racemic Lactones to Enantio-enriched Lactams

J. Am. Chem. Soc., 130(48) 16174-16175, 2008
Rhodium-catalyzed hydroalkynylation of internal Alkynes with silylacetylenes: An Alkynylrhodium(I) intermediate generated from the Hydroxorhodium(I) complex [Rh(OH)(binap)](2)

Takahiro Nishimura, Xun-Xiang Guo, Kohei Ohnishi, Tamio Hayashi

ADVANCED SYNTHESIS & CATALYSIS, 349(17-18) 2669-2672, Dec, 2007

Books and Other Publications

Transirion Metal-Catalyzed Synthesis of Allenes

Modern Allene Chemistry, Wiley-VCH, 2004
Hydrosilylations

Transition Metals for Organic Synthesis, Wiley-VCH, 2004
Transirion Metal-Catalyzed Synthesis of Allenes

Modern Allene Chemistry, Wiley-VCH, 2004
Hydrosilylations

Transition Metals for Organic Synthesis, Wiley-VCH, 2004
Ferrocenes

VCH Verlagsgesellschaft, 1995

Professional Memberships

Works

未来型不斉反応プロセス

1996 - 2000
Future Asymmetric Reaction Process

1996 - 2000

Profile Information

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Research History

Education

Awards

Misc.

Books and Other Publications

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