Papers

Peer-reviewed
Oct, 2014

N-confused phlorin: a stable dihydroporphyrin isomer containing a confused pyrrole ring

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
  • Masatoshi Ishida
    • ,
  • Kensuke Nakahara
    • ,
  • Ryuichi Sakashita
    • ,
  • Tomoya Ishizuka
    • ,
  • Motonori Watanabe
    • ,
  • Hidemitsu Uno
    • ,
  • Atsuhiro Osuka
    • ,
  • Hiroyuki Furuta
Volume
18
Number
10-11
First page
909
Last page
918
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1142/S1088424614500692
Publisher
WORLD SCI PUBL CO INC
Synthesis of bona fide N-confused phlorin derivatives through simple chemical reduction of N-confused porphyrin precursors using sodium borohydride, p-toluenesulfonyl hydrazide, etc. is described. Spectroscopic, X-ray diffraction analyses and DFT-assisted calculations of these species support the nonaromatic phlorin electronic structure.
Link information
DOI
https://doi.org/10.1142/S1088424614500692
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000346189500009&DestApp=WOS_CPL
ID information
  • DOI : 10.1142/S1088424614500692
  • ISSN : 1088-4246
  • eISSN : 1099-1409
  • Web of Science ID : WOS:000346189500009
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