1999年9月1日
ポルフィリン多量体合成法の進歩
有機合成化学協会誌
- ,
- 巻
- 57
- 号
- 9
- 開始ページ
- 749
- 終了ページ
- 762
- 記述言語
- 日本語
- 掲載種別
- 記事・総説・解説・論説等(学術雑誌)
- DOI
- 10.5059/yukigoseikyokaishi.57.749
- 出版者・発行元
- The Society of Synthetic Organic Chemistry, Japan
Recent advances in the synthesis of covalently linked multiporphyrin arrays are summarized with particular emphasis on those with well-defined geometries and with novel and interesting properties. Of these, 1) aromatic-group bridged porphyrin arrays have been proved to be useful for defining geometries of the porphyrin arrays without alternation of physical properties of porphyrin subunits, 2) ethynyl-group bridged porphyrin arrays that are relatively easy to make by palladium-catalyzed reactions display significant changes in their optical and electrochemical properties particularly when the ethynyl groups are attached at the meso-positions of porphyrins, and 3) meso-meso linked multiporphyrin arrays are promising in view of their unique optical properties, easy extension to higher oligomers, and relatively high solubility.
- リンク情報
- ID情報
-
- DOI : 10.5059/yukigoseikyokaishi.57.749
- ISSN : 0037-9980
- CiNii Articles ID : 10009344983
- CiNii Books ID : AN0024521X