論文

査読有り
2010年

Temperature dependence of intermediate-range orders in the viscosity-temperature relationship of supercooled liquids and glasses

J. Chem. Phys.
  • Hiroshi Kobayashi and Haruyuki Takahashi

132
10
開始ページ
104504
終了ページ
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1063/1.3353926
出版者・発行元
AMER INST PHYSICS

The viscosity-temperature relationship obtained by us for several glasses over a wide temperature range was analyzed by extending the Adam-Gibbs theory to the range below the glass transition temperature (T(g)). The entropy change of the intermediate-range orders (IROs) is discussed on the basis of the theory developed by Prigogine. It is estimated that the time dependence of the vibrational entropy of a glass shows a constant decrease with a smallest change, while that of its configurational entropy is 0, keeping the constant fictive temperature and the isostructural state. The result predicts the decrease of the volume of a glass at the constant time-rate through spontaneous aging at the constant temperature. We also show that the glass transition is a phase transition from an equilibrium Vogel-Fulcher-Tamman state to a nonequilibrium and (meta-)stable Arrhenius state through fluctuations at T(g), and a microscopic feature of the glass transition is the self-organization of the IROs. These findings are extremely useful in analyzing glass and nanomaterial productions because the size of the IROs in the glass state is a few nanometers.

リンク情報
DOI
https://doi.org/10.1063/1.3353926
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000275589700029&DestApp=WOS_CPL
ID情報
  • DOI : 10.1063/1.3353926
  • ISSN : 0021-9606
  • Web of Science ID : WOS:000275589700029

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