2005年7月15日
Cycloaddition of "N-Acyliminium ion pools" with carbon-carbon multiple bonds
Bulletin of the Chemical Society of Japan
- ,
- ,
- ,
- 巻
- 78
- 号
- 7
- 開始ページ
- 1206
- 終了ページ
- 1217
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.78.1206
N-Acyliminium ion pools, which are generated from α-silyl carbamates, were found to react with a variety of alkenes and alkynes to give the corresponding cycloadducts. The reaction with styrene derivatives gave rise to the formation of a significant amount of polymeric products. The use of micromixing, however, resulted in a significant increase in the yield of the cycloadduct at the expense of the polymer. Mechanistic studies indicated that a concerted mechanism seems to be most likely for alkyl-substituted alkenes, whereas a stepwise mechanism seems to be reasonable for aryl-substituted alkenes. © 2005 The Chemical Society of Japan.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.78.1206
- ISSN : 0009-2673
- SCOPUS ID : 23244439955