2017年10月
Impact of a subtle structural difference on the kinetic behavior of metastable supramolecular assemblies
POLYMER
- ,
- ,
- 巻
- 128
- 号
- 開始ページ
- 311
- 終了ページ
- 316
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.polymer.2016.12.027
- 出版者・発行元
- ELSEVIER SCI LTD
Molecular self-assembly under kinetic control has many opportunities leading to novel phenomena and applications. However, a mechanistic insight into the intricate kinetic behavior is still lacking. Herein, we demonstrate that even a subtle change in the molecular structure affects the kinetic behavior of meta-stable supramolecular assembles. Interestingly, the kinetic process influenced the size of the final outcomes (in this study, nanosheet structures) in a manner opposite to that predicted by the thermodynamic model. Our findings illustrate the difference between thermodynamically and kinetically controlled molecular self-assemblies. We believe that this study will expand the potential applications of molecular self-assemblies. (C) 2016 Elsevier Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.polymer.2016.12.027
- ISSN : 0032-3861
- eISSN : 1873-2291
- Web of Science ID : WOS:000413399300031