論文

査読有り
2012年10月4日

Microcoils and microsamples in solid-state NMR

SOLID STATE NUCLEAR MAGNETIC RESONANCE
  • Kazuyuki Takeda

47-48
開始ページ
1
終了ページ
9
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.ssnmr.2012.09.002
出版者・発行元
ACADEMIC PRESS INC ELSEVIER SCIENCE

Recent reports on microcoils are reviewed. The first part of the review includes a discussion of how the geometries of the sample and coil affect the NMR signal intensity. In addition to derivation of the well-known result that the signal intensity increases as the coil size decreases, the prediction that dilution of a small sample with magnetically inert matter leads to better sensitivity if a tiny coil is not available is given. The second part of the review focuses on the issues specific to solid-state NMR. They include realization of magic-angle spinning (MAS) using a microcoil and harnessing of such strong pulses that are feasible only with a microcoil. Two strategies for microcoil MAS, the piggyback method and magic-angle coil spinning (MACS), are reviewed. In addition, MAS of flat, disk-shaped samples is discussed in the context of solid-state NMR of small-volume samples. Strong RF irradiation, which has been exploited in wide-line spectral excitation, multiple-quantum MAS (MQMAS), and dipolar decoupling experiments, has been accompanied by new challenges regarding the Bloch-Siegert effect, the minimum time resolution of the spectrometer, and the time scale of pulse transient effects. For a possible solution to the latter problem, recent reports on active compensation of pulse transients are described. (C) 2012 Elsevier Inc. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.ssnmr.2012.09.002
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201202216510228570
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/23083521
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000310650600001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.ssnmr.2012.09.002
  • ISSN : 0926-2040
  • eISSN : 1527-3326
  • J-Global ID : 201202216510228570
  • PubMed ID : 23083521
  • Web of Science ID : WOS:000310650600001

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