2015年4月
Anodic Photocurrent Generation by Porphyrin-Terminated Helical Peptide Monolayers on Gold
JOURNAL OF PHYSICAL CHEMISTRY C
- ,
- ,
- 巻
- 119
- 号
- 15
- 開始ページ
- 8054
- 終了ページ
- 8061
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.jpcc.5b01100
- 出版者・発行元
- AMER CHEMICAL SOC
Photocurrent generation of porphyrin-terminated helical peptide self-assembled monolayers (SAMs) was studied in an aqueous solution. The anodic photocurrent was prevailing, but the cathodic photocurrent was observed with applying negative bias voltage on the working electrode. The bias dependence of the photocurrent was explained successfully by theoretical calculation with taking into account the redox potential shift by J-aggregate of porpyrins, the helix dipole, and photoenergy migration in the SAM. The dark current was insignificant even at the forward bias voltage.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.jpcc.5b01100
- ISSN : 1932-7447
- ORCIDのPut Code : 43399236
- Web of Science ID : WOS:000353249500010