2020年1月
STEREOSELECTIVE CONSTRUCTION OF A BERBERINE C-8 BENZYL GROUP FOR THE SYNTHESIS OF JAVABERINE DERIVATIVES
HETEROCYCLES
- ,
- ,
- ,
- ,
- ,
- 巻
- 101
- 号
- 2
- 開始ページ
- 512
- 終了ページ
- 523
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.3987/COM-19-S(F)36
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
Diastereoselective synthesis of 8-benzyltetrahydroprotoberberines was examined. Although Stevens rearrangement of N-benzylxylopinine resulted in poor yield and diastereoselectivity, benzylation of tetracyclic iminium successfully gave H8-H14 trans-benzyltetrahydroprotoberberines with high stereoselectivity.
- リンク情報
- ID情報
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- DOI : 10.3987/COM-19-S(F)36
- ISSN : 0385-5414
- eISSN : 1881-0942
- Web of Science ID : WOS:000571525200014