2007年10月
Precise sound velocity measurement for liquid Se50Te50 under high pressure
JOURNAL OF NON-CRYSTALLINE SOLIDS
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- ,
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- 巻
- 353
- 号
- 32-40
- 開始ページ
- 3358
- 終了ページ
- 3361
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/j.jnoncrysol.2007.05.083
- 出版者・発行元
- ELSEVIER SCIENCE BV
We have measured the sound velocity in liquid Se50Te50 at 19.5, 32.6, 45.6, and 58.2 MHz simultaneously by means of an ultrasonic pulse transmission/echo method. By using a phase-sensitive-detection technique the relative error was reduced to less than 0. 1%. The temperature dependence of sound velocity at 100 MPa exhibits a minimum at 600 degrees C and a maximum at 1035 degrees C, which are related to the large structural change accompanied by the semiconductor-metal (S-M) transition. In addition, sound dispersion has been observed at temperatures from 500 degrees C to 900 degrees C for the first time, where anomalous sound attenuation was previously reported. This result implies that a structural relaxation on nanosecond timescale takes place in the S-M transition region. (c) 2007 Published by Elsevier B.V.
- リンク情報
- ID情報
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- DOI : 10.1016/j.jnoncrysol.2007.05.083
- ISSN : 0022-3093
- Web of Science ID : WOS:000250235200075