2020年12月1日
Evaluation on hybrid−electrolyte structure using the liquid electrolyte interlayer containing LiBH<inf>4</inf> at Li<inf>7</inf>La<inf>3</inf>Zr<inf>2</inf>O<inf>12</inf> | Li interface at high operating temperature
Journal of Power Sources
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- 巻
- 478
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- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jpowsour.2020.228751
© 2020 Elsevier B.V. Li metal battery with garnet-type Li7La3Zr2O12 (LLZ) as a solid electrolyte has attracted attentions as a promising candidate for high-energy batteries. However, the interfacial resistance between LLZ and Li is huge due to a point-point contact, leading to poor battery performances such as rate capability and cycleability. Here, we have studied the hybrid-electrolyte structure using the liquid electrolyte interlayer containing LiBH4 between LLZ and Li at high operating temperature of 120 °C. This hybrid-electrolyte structure offers high current density usage and a long-term cycleability. The Li|LLZ|Li symmetric cell shows high critical current density of 13 mA cm−2 and a long term cycle. The liquid electrolyte interlayer containing LiBH4 provides an improved coulombic efficiency of Li striping/plating due to an excellent reductive stability. Our findings suggest that the interfacial conditions on LLZ|Li could be effectively improved by using the modified liquid electrolyte interlayer.
- リンク情報
- ID情報
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- DOI : 10.1016/j.jpowsour.2020.228751
- ISSN : 0378-7753
- SCOPUS ID : 85089953641