論文

査読有り
2013年

Hierarchically self-assembled helical aromatic conjugated polymers

JOURNAL OF MATERIALS CHEMISTRY C
  • Kazuyoshi Watanabe
  • ,
  • Kiyoshi Suda
  • ,
  • Kazuo Akagi

1
16
開始ページ
2797
終了ページ
2805
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1039/c3tc00045a
出版者・発行元
ROYAL SOC CHEMISTRY

We review recent progress in hierarchically self-assembled helical aromatic pi-conjugated polymers (ACPs) by focusing on (i) the intrachain helicity of ACPs in which the main chain forms a helicene-like helical conformation and (ii) the interchain helicity of ACPs in which the main chains are helically pi-stacked with one another. In Part 1, intrachain helical poly(meta-phenylene ethynylene) derivatives are discussed in terms of thermodynamic stability, usage of a chiral template, and feasibility of chiral recognition. Intrachain helical poly(meta-phenylene) derivatives are discussed from viewpoints of hierarchically self-assembled whiskers, magnetically forced macroscopic alignment, and chemical modification producing poly(thiaheterohelicene)s with stiff intrachain helicity. In Part 2, both polythiophene derivatives and poly(para-phenylene vinylene) derivatives are discussed in terms of interchain helicity and the effect of chiral organisation on chiroptical properties. Subsequently, thienylene-based diblock copolymers are discussed in terms of formation of hierarchical superhelices. Finally, thienylene- and phenylene-based homopolymers and copolymers are discussed in terms of an interchain helically pi-stacked structure; reversible photoswitching of circularly polarised luminescence; and the evolution of RGB- and white-coloured, circularly polarised luminescence.

リンク情報
DOI
https://doi.org/10.1039/c3tc00045a
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000316960300001&DestApp=WOS_CPL
ID情報
  • DOI : 10.1039/c3tc00045a
  • ISSN : 2050-7526
  • eISSN : 2050-7534
  • Web of Science ID : WOS:000316960300001

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