2017年9月
Oxygen Storage Property and Chemical Stability of SrFe1-xTixO3-delta with Robust Perovskite Structure
JOURNAL OF PHYSICAL CHEMISTRY C
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- 巻
- 121
- 号
- 35
- 開始ページ
- 19358
- 終了ページ
- 19364
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.jpcc.7b06078
- 出版者・発行元
- AMER CHEMICAL SOC
The compounds of SrFe1-xTixO3-delta with a robust perovskite structure are synthesized by Ti substitution for Fe sites in SrFeO3-delta, and they display improved oxygen storage properties and chemical stability in a CO2 atmosphere. The oxygen storage rate of SrFe0.8Ti0.2O3-delta is over 5 times faster than that of SrFeO3-delta. Further, in the presence of CO2, SrFe1-xTixO3-delta with x >= 0.2 maintains its oxygen storage property, whereas, for x <= 0.1, the oxygen release rate drastically deteriorates due to the formation of SrCO3. The perovskite structures (space group I4/mmm) of SrFe1-xTixO3-delta (x >= 0.2) are preserved even after reduction treatment under a H-2 atmosphere at 773 K. In contrast, the material with x <= 0.1 undergoes a phase transformation from perovskite (14/mmm) to brownmillerite structures (Ima2), and the latter easily reacts with CO2 to form a large amount of SrCO3 on the surface. Thus, the robust perovskite structure maintains its original framework despite the reduction treatment, resulting in improved oxygen storage rate as well as the CO2 resistance.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.jpcc.7b06078
- ISSN : 1932-7447
- Web of Science ID : WOS:000410597600045