2001年3月
Facile and selective formation of a linear-triquinane skeleton by a rationally designed round trip radical reaction
TETRAHEDRON LETTERS
- ,
- ,
- ,
- 巻
- 42
- 号
- 11
- 開始ページ
- 2157
- 終了ページ
- 2160
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/S0040-4039(01)00107-1
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
The radical reaction of 1-iodo-1,5,10-trienoate afforded a linear fused five-membered carbocycle. Another key feature of this reaction is the remarkable acceleration of the reaction rate and enhancement of selectivity caused by the introduction of a conjugated ester moiety at the terminal olefin. This cascade reaction proceeds through three sequential 5-exo cyclizations. The result is in stark contrast with the previously reported radical reaction of 1-iodo-1,5,9,14-tetraenoate, which afforded a linear fused six-membered carbocycle through a 6-endo, 6-endo, 6-exo cyclization. (C) 2001 Elsevier Science Ltd. All rights reserved.
- リンク情報
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- DOI
- https://doi.org/10.1016/S0040-4039(01)00107-1
- J-GLOBAL
- https://jglobal.jst.go.jp/detail?JGLOBAL_ID=200902181628864442
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000167494300029&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-0035843421&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0002-1798-7919
- ID情報
-
- DOI : 10.1016/S0040-4039(01)00107-1
- ISSN : 0040-4039
- J-Global ID : 200902181628864442
- ORCIDのPut Code : 45409608
- SCOPUS ID : 0035843421
- Web of Science ID : WOS:000167494300029