2003年3月
De novo designed contrasteric Diels-Alder reactions of 5-(2-oxazolynyl)-1,2,3,4,5-pentamethylcyclopentadiene
TETRAHEDRON LETTERS
- ,
- ,
- 巻
- 44
- 号
- 10
- 開始ページ
- 2187
- 終了ページ
- 2190
- 記述言語
- 英語
- 掲載種別
- DOI
- 10.1016/S0040-4039(03)00157-6
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
5-(2-Oxazolynyl)cyclopentadiene was designed on the basis of the orbital mixing rule to react with dienophiles with highly contrasteric manner in Diels-Alder reactions. The design was validated by the synthesis and reactions of the corresponding pentamethyl derivative, 5-(2-oxazolynyl)-1,2,3,4,5-pentamethylcyclopentadiene, to afford the products with the ratios of syn/anti-89-93/11-7. (C) 2003 Elsevier Science Ltd. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S0040-4039(03)00157-6
- ISSN : 0040-4039
- Web of Science ID : WOS:000181242600047