武隈真一 (Shin'ichi Takekuma) - マイポータル - researchmap

基本情報

所属: 近畿大学理工学部応用化学科助教授

学位: 工学博士(近畿大学)

J-GLOBAL ID: 200901082826863271
researchmap会員ID: 1000110055

研究キーワード

3

研究分野

1

ナノテク・材料 / 有機合成化学 /

経歴

5

1992年 - 1997年

近畿大学理工学部応用化学科講師
1997年

- 近畿大学理工学部応用化学科助教授
1997年

- Associate Professor, Faculty of Science and
1984年 - 1992年

近畿大学理工学部応用化学科助手
Engineering, Kinki Univesity

学歴

4

- 1983年

近畿大学, 工学研究科, 応用化学
- 1983年

Kinki University, Graduate School, Division of Engineering, Applied Chemistry
- 1981年

近畿大学, 理工学部, 応用化学
- 1981年

Kinki University, Faculty of Science and Engineering, Department of Applied Chemistry

論文

23

A Facile Preparation, Characteristic Properties, and Crystal Structure of {4-[(E)-2-(3-Guaiazulenyl)diazenyl]phenyl}(3-guaiazulenyl)methylium Hexafluorophosphate

Shin-ichi Takekuma, Atsuki Seki, Toshie Minematsu

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 87(4) 511-527 2014年4月
Preparation, Crystal Structure, and Spectroscopic, Chemical, and Electrochemical Properties of (2E,4E)-1-(3-Guaiazulenyl)-4-(2-thienyl)-1,3-butadiene

Shin-ichi Takekuma, Norihito Kobayashi, Toshie Minematsu, Hideko Takekuma

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 86(8) 968-982 2013年8月
Preparation, crystal structure, and spectroscopic, chemical, and electrochemical properties of (2E,4E)-1,4-di(3-guaiazulenyl)-1,3-butadiene compared with those of (E)-1,2-di(3-guaiazulenyl)ethylene

Shin-ichi Takekuma, Manami Yamamoto, Aki Nakagawa, Tomohiro Iwata, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 68(39) 8318-8329 2012年9月
Preparation, molecular structures, and characteristic properties of (E)-1-(2-furyl)- and (E)-1-(2-thienyl)-2-(3-guaiazulenyl)ethylenes and (E)-1-(3-furyl)- and (E)-1-(3-thienyl)-2-(3-guaiazulenyl)ethylenes

Shin-ichi Takekuma, Keisuke Nagata, Yusuke Yoshioka, Hironori Obata, Takaharu Minami, Tomoyoshi Tanaka, Keisuke Yashima, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 68(33) 6737-6758 2012年8月
A facile preparation, spectroscopic and chemical properties, crystal structures, and electrochemical behavior of monocarbenium ion compounds stabilized by 3-guaiazulenyl and dihydroxyphenyl (or hydroxymethoxyphenyl) groups

Shin-ichi Takekuma, Ippei Miyamoto, Akio Hamasaki, Toshie Minematsu

TETRAHEDRON 67(50) 9719-9728 2011年12月
Reaction of azulene with 1,2-bis[4-(dimethylamino)phenyl]-1,2-ethanediol in a mixed solvent of methanol and acetonitrile in the presence of hydrochloric acid: a facile one-pot synthesis and properties of new triarylethylenes possessing an azulen-1-yl group

Shin-ichi Takekuma, Masamichi Kaibara, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 67(26) 4780-4792 2011年7月
Preparation, Crystal Structures, and Spectroscopic and Chemical Properties of 2,4,6-Trifluorophenyl- or 4-(Methoxycarbonyl)phenyl-Substituted (E)-1-(3-Guaiazulenyl)ethylene and (2E,4E)-1-(3-Guaiazulenyl)-1,3-butadiene Derivatives

Shin-ichi Takekuma, Hiroto Matsuoka, Syoutarou Ogawa, Yasutaka Shibasaki, Toshie Minematsu

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 83(10) 1248-1263 2010年10月
Preparation, crystal structure, and spectroscopic, chemical, and electrochemical properties of (2E,4E)-4-[4-(dimethylamino)phenyl]-1-(3-guaiazulenyl)-1,3-butadiene compared with those of (E)-2-[4-(dimethylamino)phenyl]-1-(3-guaiazulenyl)ethylene

Shin-ichi Takekuma, Hiroto Matsuoka, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 66(16) 3004-3015 2010年4月
Preparation and Structures of New Azobenzene Derivatives with a 3-Guaiazulenylvinyl Group

Shin-ichi Takekuma, Kenji Fukuda, Toshie Minematsu, Hideko Takekuma

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 82(11) 1398-1408 2009年11月
Preparation, structures, and properties of new monocarbenium ion compounds stabilized by a 3-guaiazulenyl group and an azobenzene unit: comparative studies on three delocalized π-electron systems

武隈真一

Bull. Chem. Soc. Jpn. 82(7) 879-890 2009年7月
A Facile Preparation of (4-Aminophenyl)(3-guaiazulenyl)methylium Hexafluorophosphate: Comparative Studies on Spectroscopic, Chemical, and Electrochemical Properties of Monocarbenium Ion and p-Benzoquinodimethane Monoiminium Ion Compounds

Shin-ichi Takekuma, Naohiko Ijibata, Toshie Minematsu, Hideko Takekuma

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 82(5) 585-593 2009年5月
An efficient preparation, spectroscopic properties, and crystal structure of 1,1-bis{4-[2-(dimethylamino)ethoxy]phenyl}-2-(3-guaiazulenyl)ethylene

武隈真一

Res. Lett. Org. Chem. (open access article) (DOI:10.1155/2009/684359) 2009 1-5 2009年2月
Preparation, crystal structures, and properties of new conjugated π-electron systems with 3-guaiazulenyl and 4-(dimethylamino)phenyl groups

武隈真一

Bull. Chem. Soc. Jpn. 81(11) 1472-1484 2008年11月
An efficient preparation and spectroscopic and electrochemical properties of quinodimethane derivatives with four 3-(methoxycarbonyl)azulen-1-yl groups

Shin-ichi Takekuma, Kazutaka Sonoda, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 64(17) 3802-3812 2008年4月
An efficient preparation, crystal structures, and properties of monocarbenium-ion compounds stabilized by 3-guaiazulenyl and anisyl groups

Shin-Ichi Takekuma, Masayuki Tamura, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 63(48) 12058-12070 2007年11月
Reactions of azulene and guaiazulene with all-trans-retinal and trans-cinnamaldehyde: comparative studies on spectroscopic, chemical, and electrochemical properties of monocarbeniumions stabilized by expanded pi-electron systems with an azulenyl or 3-guaiazulenyl group

Shin-ichi Takekuma, Kazutaka Mizutani, Kanako Inoue, Masaru Nakamura, Masato Sasaki, Toshie Minematsu, Kunihisa Sugimoto, Hideko Takekuma

TETRAHEDRON 63(18) 3882-3893 2007年4月
Reaction of guaiazulene with o-formylbenzoic acid in diethyl ether (or methanol) in the presence of hexafluorophosphoric acid: comparative studies on H-1 and C-13 NMR spectral properties of 3-guaiazulenylmethylium- and 3-guaiazulenium-ion structures

Shin-ichi Takekuma, Kazutaka Sonoda, Chika Fukuhara, Toshie Minematsu

TETRAHEDRON 63(11) 2472-2481 2007年3月
Reactions of guaiazulene with thiophene-2,5-dicarbaldehyde and furan-2,5-dicarbaldehyde in methanol in the presence of hexafluorophosphoric acid: a facile preparation and properties of delocalized dicarbenium-ion compounds stabilized by two 3-guaiazulenyl groups and a thiophene (or furan) ring

Shin-ichi Takekuma, Kazuhiro Tone, Masato Sasaki, Toshie Minematsu, Hideko Takekuma

TETRAHEDRON 63(11) 2490-2502 2007年3月
Reactions of (E)-1,2-di(3-guaiazulenyl)ethylene and 2-(3-guaiazulenyl)-1,1-bis(4-methoxyphenyl)ethylene with tetracyanoethylene (TCNE) in benzene: comparative studies on the products and their spectroscopic properties

S Takekuma, M Hirosawa, S Morishita, M Sasaki, T Minematsu, H Takekuma

TETRAHEDRON 62(15) 3732-3738 2006年4月
Reactions of (1R,2S)-1,2-di(2-furyl)-1,2-di(3-guaiazulenyl)ethane and (1R,2S)-1,2-di(3-guaiazulenyl)-1,2-di(2-thienyl)ethane with tetracyanoethylene (TCNE) in benzene: comparative studies on the products and their spectroscopic properties

S Takekuma, K Takahashi, A Sakaguchi, M Sasaki, T Minematsu, H Takekuma

TETRAHEDRON 62(7) 1520-1526 2006年2月

もっとみる

MISC

54

gamma-Cyclodextrin-bicapped C-60-mediated asymmetric reduction of ketones with NaBH4

T Nishimura, M Nakajima, Y Maeda, S Uemura, S Takekuma, H Takekuma, Z Yoshida

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 77(11) 2047-2050 2004年11月
Reactions of azulenes with 1,2-diaryl-1,2-ethanediols in methanol in the presence of hydrochloric acid: comparative studies on products, crystal structures, and spectroscopic and electrochemical properties

M Nakatsuji, Y Hata, T Fujihara, K Yamamoto, M Sasaki, H Takekuma, M Yoshihara, T Minematsu, S Takekuma

TETRAHEDRON 60(28) 5983-6000 2004年7月
A non-metal system for nitrogen fixation

nature 428(6980) 279-280 2004年
A facile preparation and properties of (2E,4E,6E,8E)-1-(3-guaiazulenyl)-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8-nonatetraen-1-ylium hexafluorophosphate

M Nakamura, M Sasaki, H Takekuma, T Minematsu, S Takekuma

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76(10) 2051-2052 2003年10月
A facile preparation and properties of (2E,4E,6E,8E)-1-(3-guaiazulenyl)-3,7-dimethyl-9-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2,4,6,8-nonatetraen-1-ylium hexafluorophosphate

M Nakamura, M Sasaki, H Takekuma, T Minematsu, S Takekuma

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN 76(10) 2051-2052 2003年10月
The crystal structure and characteristic chemical property of 1,2-bis(3-guaiazulenylmethylium)benzene bishexafluorophosphate

M Sasaki, M Nakamura, G Hannita, H Takekuma, T Minematsu, M Yoshihara, S Takekuma

TETRAHEDRON LETTERS 44(2) 275-279 2003年1月
A facile preparation, the crystal structure, the chemical and electrochemical properties of [4-(dimethylamino)phenyl]-3-guaiazulenylmethylium tetrafluoroborate

M Sasaki, M Nakamura, T Uriu, H Takekuma, T Minematsu, M Yoshihara, S Takekuma

TETRAHEDRON 59(4) 505-516 2003年1月
The crystal structure and characteristic chemical property of 1,2-bis(3-guaiazulenylmethylium)benzene bishexafluorophosphate

M Sasaki, M Nakamura, G Hannita, H Takekuma, T Minematsu, M Yoshihara, S Takekuma

TETRAHEDRON LETTERS 44(2) 275-279 2003年1月
A facile preparation, the crystal structure, the chemical and electrochemical properties of [4-(dimethylamino)phenyl]-3-guaiazulenylmethylium tetrafluoroborate

M Sasaki, M Nakamura, T Uriu, H Takekuma, T Minematsu, M Yoshihara, S Takekuma

TETRAHEDRON 59(4) 505-516 2003年1月
An efficient preparation the Structure and the properties of 1-isopropyl-4-(3-gnaiazulenylmeehylium)benzene hexafluorophosphate and tetrafluoroborate

Tetrahedron Letters 43, 2073-2078 2002年
A Facile Preparation of 5-Isopropylidene-3, 8-dimethy-1(5H)-azulenone and Its Crystal Structure

Bull. Chem. Soc. Jpn. 75(1), 151-152 2002年
An efficient preparation the Structure and the properties of 1-isopropyl-4-(3-gnaiazulenylmeehylium)benzene hexafluorophosphate and tetrafluoroborate

Tetrahedron Letters 43, 2073-2078 2002年
A Facile Preparation of 5-Isopropylidene-3,8-dimethy-1(5H)-azulenone and Its Crystal Structure

Bull. Chem. Soc. Jpn. 75(1), 151-152 2002年
An efficient preparation and the properties of 1,2-bis(3-guaiazulenylmethylium)benzene bishexafluoro phosphate

Tetrahedron Letters 42, 5921-5924 2001年
1-┣DBO(/)-┫DB-ベンゾイルグリセリンの合成とトキイロヒラタケ(┣DBPleuroutus(/)-┫DB ┣DBsalmoneostramineus(/)-┫DB L. Vass.)の子実体形成に及ぼす効果

日本化学会誌 2001(1) 61-64 2001年
An efficient preparation and the properties of 1,2-bis(3-guaiazulenyllmethylium)benzene bisheyafluoro phosphate

Tetrahedron Letters 42,5921-5924 2001年
A highly efficient generation of gamma-cyclodextrin-bicapped C-60(1)- in aqueous solution

S Takekuma, H Takekuma, T Matsumoto, Z Yoshida

TETRAHEDRON LETTERS 41(25) 4909-4912 2000年6月
A highly selective generation of gamma-cyclodextrin-bicapped C-60(n-) (n : 1 and 2) in DMSO

S Takekuma, H Takekuma, T Matsumoto, Z Yoshida

TETRAHEDRON LETTERS 41(16) 2929-2932 2000年4月
Influence of metal complexes on the formation of gamma-cyclodextrin-bicapped C-60(n-) (n : 1 and 2) in aqueous solution

S Takekuma, H Takekuma, T Matsumoto, Z Yoshida

TETRAHEDRON LETTERS 41(7) 1043-1046 2000年2月
3,3,3”,3-(p-キノジメタン-7,7,8,8-テトライル)テトラアズレン-1,1,1”,1-テトラカルボン酸テトラメチルの効率的合成と特性

武隈真一, 佐々木正人, 武隈秀子, 山本啓司

日本化学会誌 (2) 107-114 2000年

もっとみる

所属学協会

5

共同研究・競争的資金等の研究課題

4

高次機能性拡張π-電子系の化学に関する研究

基礎科学研究 1994年
トキイロヒラタケの色素成分と光合成機能に関する研究

基礎科学研究 1994年
Studies on the Chemistry of Expanded π-Electron Systems with Higher-order Function

Basic Science Research Program 1994年
Studies on the Unique Pigment Component of Pleurotus salmoneostramineus L. Vass. and Its Photosynthetic Function

Basic Science Research Program 1994年