論文

査読有り
1993年2月

ATOMIC-SIZE EFFECTS ON MEDIUM-RANGE ORDER IN GLASSES

PHYSICAL REVIEW B
  • H IYETOMI
  • ,
  • P VASHISHTA

47
6
開始ページ
3063
終了ページ
3069
記述言語
英語
掲載種別
研究論文(学術雑誌)
出版者・発行元
AMER PHYSICAL SOC

Effects of atomic sizes on structural correlations in AX2-type disordered systems such as SiO2, GeSe2, and Ag2Se are studied using a charged-hard-sphere model and the hypernetted-chain scheme. Structural change is elucidated as a function of the size ratio through the first sharp diffraction peak in the number-number structure factor (medium-range correlations), the A-X coordination [formation of A(X1/2)4 tetrahedra], and the principal peak in the charge-charge structure factor (charge ordering). We find a gradual change from SiO2-type to Ag2Se-type disordered structure in the range of 0.5 < R < 1.0, where R (=sigma(A)/sigma(X)) is a ratio of the steric radius of A species to that of X species. As R increases, the medium-range order, which is closely related to the formation of A(X1/2)4 tetrahedra, disappears. In the transition region frustration between the steric and Coulombic interactions depresses the charge ordering.

リンク情報
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:A1993KM95300015&DestApp=WOS_CPL
ID情報
  • ISSN : 1098-0121
  • eISSN : 1550-235X
  • Web of Science ID : WOS:A1993KM95300015

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