論文

査読有り 国際誌
2021年3月1日

Effect of Nonlinear Elasticity on the Swelling Behaviors of Highly Swollen Polyelectrolyte Gels

Gels
  • Jian Tang
  • ,
  • Takuya Katashima
  • ,
  • Xiang Li
  • ,
  • Yoshiro Mitsukami
  • ,
  • Yuki Yokoyama
  • ,
  • Ung-il Chung
  • ,
  • Mitsuhiro Shibayama
  • ,
  • Takamasa Sakai

7
1
開始ページ
25
終了ページ
25
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.3390/gels7010025
出版者・発行元
MDPI AG

Polyelectrolyte gels exhibit swelling behaviors that are dependent on the external environment. The swelling behaviors of highly charged polyelectrolyte gels can be well explained using the Flory–Rehner model combined with the Gibbs–Donnan effect and Manning’s counterion condensation effect (the FRGDM model). This study investigated the swelling properties of a series of model polyelectrolyte gels, namely tetra-polyacrylic acid-polyethylene glycol gels (Tetra-PAA-PEG gels), and determined the applicability of the FRGDM model. The swelling ratio (Vs/V0) was well reproduced by the FRGDM model in the moderate swelling regime (Vs/V0 < 10). However, in the high swelling regime (Vs/V0 > 10), the FRGDM model is approx. 1.6 times larger than the experimental results. When we introduced the finite extensibility to the elastic free energy in the FRGDM model, the swelling behavior was successfully reproduced even in the high swelling regime. Our results reveal that finite extensibility is one of the factors determining the swelling equilibrium of highly charged polyelectrolyte gels. The modified FRGDM model reproduces well the swelling behavior of a wide range of polyelectrolyte gels.

リンク情報
DOI
https://doi.org/10.3390/gels7010025
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000633110100001&DestApp=WOS_CPL
URL
https://www.mdpi.com/2310-2861/7/1/25/pdf
ID情報
  • DOI : 10.3390/gels7010025
  • eISSN : 2310-2861
  • ORCIDのPut Code : 90053417
  • Web of Science ID : WOS:000633110100001

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