Yuji Naruse

Profile Information

Affiliation: 准教授, 工学部化学・生命工学科物質化学コース, 岐阜大学
: 准教授, 工学研究科

Degree: (BLANK)(Nagoya University)

J-GLOBAL ID: 200901097487033393
researchmap Member ID: 1000022512

Hnantiomeric enrichiment／Highly chiral compounds are prepared by complexation with chiral Lewis acids.／Activation of the C-O bonds／The ether bond is activated by the Super bases to apply for the organic synthesis.／Origin of the small ring strain／The strain in the small ring compounds is rationalized in the terms of .pi.- and .sigma.-relaxations.／Geminal bond participation／The bonds geminal to the reaction center control the selectivity/reactivity.

Research Interests

Research Areas

Research History

2007

Faculty of Engineering, Gifu University
Apr, 1986 - Mar, 1989

日本学術振興会特別研究員
assistant professor, Gifu University Faculty of Engineering, Department of Chemistry

Education

Apr, 1984 - Mar, 1989

Nagoya University
- 1989

Graduate School, Division of Engineering, Nagoya University
Apr, 1980 - Mar, 1984

School of Engineering, Nagoya University

Major Awards

Apr, 2018

The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology Prize for Science and Technology (Public Understanding Promotion Category), Public Understanding Promotion on Radio Science for Young Children by Live Contacts with the Astronauts, Ministry of Education, Culture, Sports, Science and Technology

Naoyuki ISO, Yuji NARUSE, Tokimasa, KIMURA

Papers

(Alkali metal)decarboxylation reaction: Lone pair participation and design of diastereoselective enolate formation

Naruse, Yuji, Ando, Tsubasa

CheRxiv, 1-9, Sep 2, 2022 Lead authorCorresponding author
Deprotonation from Diphenylsilane with Organosilyllithium Agents

Atsushi Takamori, Shoki Ito, Yuji Naruse

ChemRxiv, 1-5, Jul 27, 2022 Last authorCorresponding author
Requirements of Orbital Phase Continuity Revisited: A FMO Approach

Yuji Naruse

chemRxiv, 1-4, Apr 2, 2021 Lead authorCorresponding author
Design of a new molecule that exhibits observable CD spectra under σ-σ* excitation: 2,6-Disilyl-2,6-disilaspiro[3.3]heptanes

Yuji Naruse, Atsushi Takamori, Itsuki Nagasawa

Phosphorus, Sulfur, and Silicon and the Related Elements, 195(7) 523-525, Jul 2, 2020 Peer-reviewedLead author
Design of Boradecarboxylation Reaction

Yuji Naruse, Atsushi Takamori, Kenji Oda

Jan 22, 2020 Lead author
Orbital Phase Perspective of Goodenough-Kanamori-Anderson Rules (GKA Rules) in Superexchange Interaction

Yuji Naruse, Atsushi Takamori

chemRxiv, Nov 13, 2019 Lead authorCorresponding author
Felkin-Anh Model from an Orbital Phase Perspective: Diastereoselectivity in Nucleophilic Addition to 2,3-Bis(trifluoromethyl)bicyclo[2.2.1]heptan-7-one

Yuji Naruse, Hayata Hibino, Atsushi Takamori

chemRxiv, Sep 13, 2019 Lead author
Torquoselectivity of the Ring-Opening Reaction of 3,3-Dihalosubstituted Cyclobutenes: Lone Pair Repulsion and Cyclic Orbital Interaction

Yuji Naruse, Atsushi Takamori

ChemRxiv, Jul 31, 2019 Lead author
Orbital theory for diastereoselectivity in electrophilic addition

Yuji Naruse, Yousuke Hasegawa, Kurumi Ikemoto

TETRAHEDRON LETTERS, 57(19) 2029-2033, May, 2016 Peer-reviewed
Geminal bond participation is essential for the contradictory torquoselectivities in retro-Nazarov reactions

Yuji Naruse, Masanari Tokunaga

TETRAHEDRON LETTERS, 56(24) 3813-3815, Jun, 2015 Peer-reviewed
First observable CD spectra from n-sigma* excitation: TD-DFT calculation and determination of absolute configuration of 2,6-dithiaspiro[3.3]heptane 2,6-dioxide

Yuji Naruse, Yousuke Hasegawa

ARKIVOC, 2015 151-160, 2015 Peer-reviewedInvitedLead authorCorresponding author
Design of a new axially chiral molecule by conformational fixation: 2,6-dithiaspiro[3.3]heptane 2,6-dioxide and its heavier analogues

Yuji Naruse, Yousuke Hasegawa, Motoya Araki

TETRAHEDRON-ASYMMETRY, 24(13-14) 781-784, Jul, 2013 Peer-reviewedLead authorCorresponding author
Design of a new axially chiral molecule by conformational fixation: 2,6-diphospha- and 2,6-diarsaspiro[3.3]heptanes

Yuji Naruse, Yuuki Kugiya

TETRAHEDRON-ASYMMETRY, 24(4) 169-171, Feb, 2013 Peer-reviewedLead authorCorresponding author
Predominance of the Participation of the Geminal over Vicinal Bonds: Torquoselectivity of Retro-Nazarov Reactions

Yuji Naruse, Yu Ichihashi, Takashi Shimizu, Satoshi Inagaki

ORGANIC LETTERS, 14(14) 3728-3731, Jul, 2012 Peer-reviewedLead author
Geminal bond participation in Carroll rearrangement

Yuji Naruse, Yasuhiro Todo, Miyu Shiomi

TETRAHEDRON LETTERS, 52(34) 4456-4460, Aug, 2011 Peer-reviewed
Thermal [3,3]-rearrangement of 1,1-disubstituted allyl carboxylates: lone pair participation and the geminal bond participation

Yuji Naruse, Aya Deki, Katsura Yamada

TETRAHEDRON, 66(34) 7035-7040, Aug, 2010 Peer-reviewedLead authorCorresponding author
Molecular Features of Neonicotinoid Pharmacophore Variants Interacting with the Insect Nicotinic Receptor

Ikuya Ohno, Motohiro Tomizawa, Kathleen A. Durkin, Yuji Naruse, John E. Casida, Shinzo Kagabu

CHEMICAL RESEARCH IN TOXICOLOGY, 22(3) 476-482, Mar, 2009 Peer-reviewed
Relaxation of Ring Strains

Yuji Naruse, Satoshi Inagaki

ORBITALS IN CHEMISTRY, 289 265-291, 2009 Peer-reviewedInvited
Insecticidal and neuroblocking potencies of variants of the thiazolidine moiety of thiacloprid and quantitative relationship study for the key neonicotinoid pharmacophore

Shinzo Kagabu, Keiiehiro Nishimura, Yuji Naruse, Ikuya Ohno

JOURNAL OF PESTICIDE SCIENCE, 33(1) 58-66, 2008 Peer-reviewed
Theoretical design of doubly bonded hypervalent atoms

Hiroaki Kameyama, Yuji Naruse, Satoshi Inagaki

ORGANOMETALLICS, 26(23) 5543-5547, Nov, 2007 Peer-reviewed

Misc.

Seminar for the Chemical Education of Tokai Branch 2017

NARUSE Yuji

62(12) 618-619, Dec, 2014 Invited
PI-FACIAL SELECTIVITIES OF NUCLEOPHILIC-ADDITION TO ALLENECARBOXYLATES

Y NARUSE, S KAKITA, A TSUNEKAWA

SYNLETT, (7) 711-713, Jul, 1995
A FACILE ACCESS TO CHIRAL ALLENEDICARBOXYLATES BY DERACEMIZATION PROCESS

Y NARUSE, H WATANABE, S INAGAKI

TETRAHEDRON-ASYMMETRY, 3(5) 603-606, May, 1992 Lead authorCorresponding author
Proceeding by Elimination

Manfred Schlosser, Yuji Naruse

Journal of Synthetic Organic Chemistry, Japan, 46(6) 528-539, 1988

Books and Other Publications

環ひずみの緩和

Naruse Yuji(Department of Chemistry Gifu University, Inagaki Satoshi(Department of Chemisty Gifu Univ, rsi

Dec 15, 2009

Presentations

Mechanism of Decarboxylation Reaction Revisited: Lone Pair Participation and Design of Boradecarboxylation Reaction

Yuji Naruse, Atsushi Takamori, Kenji Oda

ICPOC25, Jul 14, 2022
Orbital Theory Perspective of Decarboxylation Reactions: Lone Pair(s) PArticipation and Design of Bora- and (alkali Metal)decarboxylation Reactions

Yuji Naruse, Atsushi Takamori, Tsubasa Ando

WATOC2020, Jul 7, 2022 Invited
Alderエン反応におけるジェミナル結合関与

理論指向化学国際学会, Jan, 2005

Teaching Experience

Professional Memberships

Research Projects

Origin of diastereoselectivity in catalytic reaction

Memorial Grant, Endo Saijiro Memorial Foundation for Science and Technology, Oct, 2020 - Mar, 2021
ポリマー担持HWE試薬 : シス選択性の制御とリサイクラブル試薬の開発

科学研究費補助金(特定領域研究), 特定領域研究, 文部科学省, 2007 - 2008

安藤香織, 成瀬有二
遷移状態の結合モデル解析とジェミナル結合関与反応群の設計

科学研究費補助金(特定領域研究), 特定領域研究, 文部科学省, 2006 - 2006

稲垣都士, 成瀬有二
Geminal Bond Participation at the Transition States

Grants-in-Aid for Scientific Research(基盤研究(C)), 基盤研究(C), Ministry of Education, Culture, Sports, Science and Technology, 1998 - 1999

Satoshi INAGAKI, 成瀬有二, 石田勝
メチルエーテルからのエチレンの発生機構

科学研究費補助金(奨励研究(A)), 奨励研究(A), 文部科学省, 1997 - 1998

成瀬有二
ジェミナル結合関与による選択性の発現

1998
非対称ジエンのディ-ルス・アルダ-反応のπ面選択性の電子制御

科学研究費補助金(基盤研究(C)), 基盤研究(C), 文部科学省, 1996 - 1996

石田勝, 成瀬有二, 稲垣都士
反転した炭素四面体配置の起源と設計

科学研究費補助金(基盤研究(C)), 基盤研究(C), 文部科学省, 1996 - 1996

稲垣都士, 成瀬有二, 石田勝
geminal bond participation in organic reactions

1996
反応性と面選択性

科学研究費補助金(重点領域研究), 重点領域研究, 文部科学省, 1995 - 1995

稲垣都士, 成瀬有二, 石田勝
ジェミナル結合間の電子非局在化と小員環化合物のひずみ

科学研究費補助金(一般研究(C)), 一般研究(C), 文部科学省, 1993 - 1993

稲垣都士, 成瀬有二, 石田勝
非対称化エノール化反応を用いるイソカルバサイクリンの短段階合成

科学研究費助成事業, 奨励研究(A), 日本学術振興会, 1990 - 1990

成瀬有二
C,Nージアニオン中間体を経由するインド-ル側鎖への新規官能基導入反応の開発

科学研究費補助金(一般研究(C)), 一般研究(C), 文部科学省, 1990 - 1990

稲垣都士, 成瀬有二
典型金属反応剤を用いる不斉有機合成

科学研究費助成事業, 奨励研究(A), 日本学術振興会, 1987 - 1988

成瀬有二
Deprotonation from alkoxysilanes
Novel reactivities of allenes
Preparation of chiral compounds by deracemization process
アルコキシシランからの脱プロトン化反応
アレン化合物の新規反応性の開拓
不斉化反応による光学活性化合物の創出

Industrial Property Rights

特許6918280 Production of polysilanes

NARUSE Yuji, KAMEYAMA Hiroaki, HIBINO Hayata

Social Activities

電波のふしぎを体験！モリゾー＆キッコロの親子電子工作とサイエンス実験

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 1, 2012 - Mar 31, 2013
モリゾー＆キッコロの親子電子工作と電波サイエンス実験

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 1, 2011 - Mar 31, 2012
電波を楽しもう！モリゾー＆キッコロのピカピカ電子工作とサイエンス実験

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 1, 2010 - Mar 31, 2011
国際宇宙ステーションの日本人宇宙飛行士と交信！」

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 9, 2009 - Mar 31, 2010
電波を体験！モリゾー＆キッコロの電子工作と科学実験教室

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 9, 2009 - Mar 31, 2010
電波を感じよう！モリゾー＆キッコロの電子工作教室

ＪＡＲＬ東海地方本部, ＪＡＲＬ東海地方本部, May 7, 2008 - Mar 31, 2009